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Colorimetric recognition of oxalate in water by a new carbazole-Zn(II) based chemosensing ensemble

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2013-09-01

Journal: JOURNAL OF CHEMICAL RESEARCH

Included Journals: Scopus、SCIE

Volume: 37

Issue: 9

Page Number: 542-545

ISSN: 1747-5198

Key Words: chemosensing ensemble; artificial sensors; oxalate; colorimetric detection; carbazole-containing dinuclear zinc(II) complex

Abstract: A chemosensing ensemble consisting of a carbazole-containing dinuclear zinc(II) complex and chromeazurol S displays colorimetric recognition of oxalate in water at pH 7.0. Upon addition of oxalate, the ensemble solution exhibits a naked eye detectable colour change from blue to yellow. The oxalate sensing process is hardly affected by other dicarboxylates; addition of dicarboxylates such as malonate, succinate, glutarate, adipate, phthalate, isophthalate and terephthalate does not induce significant colour changes.

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