Release Time:2019-03-11  Hits:

Indexed by: Journal Article

Date of Publication: 2017-09-14

Journal: CHEMICAL COMMUNICATIONS

Included Journals: PubMed、SCIE

Volume: 53

Issue: 71

Page Number: 9854-9857

ISSN: 1359-7345

Abstract: A novel well-defined thiolate-bridged dicobalt azido complex is converted to a rare sulfilimide-bridged dicobalt complex via nitrogen atom migratory insertion into the Co-S bond upon thermolysis. Intriguingly, the homolytic cleavage of hydrogen is achieved by this azide under mild conditions to furnish a partially hydrogenated azido complex.