Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2017-09-01

Journal: INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals: Scopus、SCIE

Volume: 83

Page Number: 66-69

ISSN: 1387-7003

Key Words: Iron-ruthenium complexes; Interconversion; Redox properties; N-N bond cleavage

Abstract: The novel thiolate-bridged iron-ruthenium heteronuclear complex [(PPh3)(bdt)Ru(mu-eta(2):eta(4)-bdt)FeCp*] (1, Cp* = eta(5)-(CMe5)-Me-5, bdt = benzene-1,2-dithiolate) was prepared by one -electron reduction of complex [(PPh3)(bdt)Ru(mu-eta(2):eta(4)-bdt)FeCp*][FeCl3] (1[FeCl3]) using CoCp2 as reducing agent. Meanwhile, complex 1 can also be one-electron oxidized by Fc center dot PF6 or HBF4 to regenerate the ionic complex 1[PF6] or 1[BE4]. Importantly, complex 1 shows good reactivity toward the catalytic N-N bond cleavage of hydrazine into ammonia. (C) 2017 Elsevier B.V. All rights reserved.