Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates
Release Time:2019-03-12 Hits:
Indexed by: Journal Article
Date of Publication: 2017-08-01
Journal: ORGANIC CHEMISTRY FRONTIERS
Included Journals: Scopus、SCIE
Volume: 4
Issue: 8
Page Number: 1580-1585
ISSN: 2052-4129
Abstract: An efficient approach to allylic boronates via iron-catalyzed boration of allylic esters is described. The reactions of allylic esters and bis(pinacolato) diboron (B(2)pin(2)) proceed smoothly catalyzed by FeCl2/PPh3. Thus, a wide range of allylic boronates with broad functional-group compatibility are obtained.