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Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

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Indexed by:期刊论文

Date of Publication:2017-08-01

Journal:ORGANIC CHEMISTRY FRONTIERS

Included Journals:SCIE、Scopus

Volume:4

Issue:8

Page Number:1580-1585

ISSN No.:2052-4129

Abstract:An efficient approach to allylic boronates via iron-catalyzed boration of allylic esters is described. The reactions of allylic esters and bis(pinacolato) diboron (B(2)pin(2)) proceed smoothly catalyzed by FeCl2/PPh3. Thus, a wide range of allylic boronates with broad functional-group compatibility are obtained.

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