Methylene insertion into an Fe2S2 cluster: formation of a thiolate-bridged diiron complex containing an Fe-CH2-S moiety
Release Time:2019-03-12 Hits:
Indexed by: Journal Article
Date of Publication: 2018-12-04
Journal: CHEMICAL COMMUNICATIONS
Included Journals: Scopus、SCIE
Volume: 54
Issue: 93
Page Number: 13119-13122
ISSN: 1359-7345
Abstract: Reduction of a thiolate-bridged (FeFeIII)-Fe-II complex leads to the cleavage of an Fe-S bond by the insertion of the methylene unit from CH2Cl2 to give a neutral (FeFeIII)-Fe-II complex with a novel Fe-CH2-S fragment. The structural and electrochemical differences of the alkylated and the non-alkylated Fe2S2 complexes are also examined.
Prev One:Base-Promoted Double-Bond-Migration/Hydrolysis/Isomerization of 4-Aryl-1,1,1-trifluorobut-2-en-2-yl Trifluoromethanesulfonates: A Metal-Free Approach to beta-Trifluoromethyl Ketones
Next One:Expedient Synthesis of 1,4-Benzodiazepines via a Tandem Condensation/[1,5]-Hydride Transfer/Cyclization Process