Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-03-16

Journal: JOURNAL OF ORGANIC CHEMISTRY

Included Journals: Scopus、EI、SCIE、PubMed

Volume: 77

Issue: 6

Page Number: 2942-2946

ISSN: 0022-3263

Abstract: With the direct use of allylic alcohols as allylating agents, the Friedel Crafts-type allylic alkylation of nitrogen-containing aromatic compounds catalyzed by a [Mo3S4Pd(eta(3)-allyl)] cluster is achieved. With a 3 mol % catalyst loading in acetonitrile at re lux or 60 degrees C, a variety of N,N-dialkylanilines and indoles reacted smoothly with allylic alcohols to afford the Friedel-Crafts-type allylation products in good to excellent yields with high levels of regioselectivity.