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Indexed by:期刊论文

Date of Publication:2010-06-18

Journal:ORGANIC LETTERS

Included Journals:SCIE、PubMed、Scopus

Volume:12

Issue:12

Page Number:2726-2729

ISSN No.:1523-7060

Abstract:A highly efficient and regioselective allylation reaction of amines and active methylene compounds directly using allylic alcohols under mild conditions catalyzed by the novel cubane-type sulfido [(Cp*Mo)(3)(mu(3)center dot S)(4)Pd(eta(3)-allyl)][PF6](2) clusters has been developed. A variety of allylic alcohols and nucleophiles including amines and active methylene compounds are investigated, and in the case of allylic alcohols bearing substituents at either the alpha- or gamma-position only linear products are obtained.