Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2010-06-18

Journal: ORGANIC LETTERS

Included Journals: Scopus、PubMed、SCIE

Volume: 12

Issue: 12

Page Number: 2726-2729

ISSN: 1523-7060

Abstract: A highly efficient and regioselective allylation reaction of amines and active methylene compounds directly using allylic alcohols under mild conditions catalyzed by the novel cubane-type sulfido [(Cp*Mo)(3)(mu(3)center dot S)(4)Pd(eta(3)-allyl)][PF6](2) clusters has been developed. A variety of allylic alcohols and nucleophiles including amines and active methylene compounds are investigated, and in the case of allylic alcohols bearing substituents at either the alpha- or gamma-position only linear products are obtained.