Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2010-04-14

Journal: TETRAHEDRON LETTERS

Included Journals: Scopus、SCIE

Volume: 51

Issue: 15

Page Number: 1982-1984

ISSN: 0040-4039

Key Words: Allylic alcohol; Allylation; Cubane-type sulfido cluster; Boric acid

Abstract: A highly efficient and regioselective allylation reaction of amines with allylic alcohols under mild conditions catalyzed by the cubane-type sulfido cluster [(Cp*Mo)(3)S4Pd(dba)][PF6] with H3BO3 as an additive has been developed. A variety of amines and allylic alcohols are investigated, and in the case of allylic alcohols bearing substituents at either alpha- or gamma-position only linear allylic amination products are obtained. (C) 2010 Elsevier Ltd. All rights reserved.