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Indexed by:期刊论文

Date of Publication:2010-04-14

Journal:TETRAHEDRON LETTERS

Included Journals:SCIE、Scopus

Volume:51

Issue:15

Page Number:1982-1984

ISSN No.:0040-4039

Key Words:Allylic alcohol; Allylation; Cubane-type sulfido cluster; Boric acid

Abstract:A highly efficient and regioselective allylation reaction of amines with allylic alcohols under mild conditions catalyzed by the cubane-type sulfido cluster [(Cp*Mo)(3)S4Pd(dba)][PF6] with H3BO3 as an additive has been developed. A variety of amines and allylic alcohols are investigated, and in the case of allylic alcohols bearing substituents at either alpha- or gamma-position only linear allylic amination products are obtained. (C) 2010 Elsevier Ltd. All rights reserved.