Migratory insertion and hydrogenation of a bridging azide in a thiolate-bridged dicobalt reaction platform
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论文类型：期刊论文
发表时间：2017-09-14
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：PubMed、SCIE
卷号：53
期号：71
页面范围：9854-9857
ISSN号：1359-7345
摘要：A novel well-defined thiolate-bridged dicobalt azido complex is converted to a rare sulfilimide-bridged dicobalt complex via nitrogen atom migratory insertion into the Co-S bond upon thermolysis. Intriguingly, the homolytic cleavage of hydrogen is achieved by this azide under mild conditions to furnish a partially hydrogenated azido complex.