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论文类型：期刊论文

发表时间：2017-12-01

发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS

收录刊物：SCIE、Scopus

卷号：86

页面范围：133-136

ISSN号：1387-7003

关键字：Iron complexes; Pendent amine; Proton relay; Interconversion

摘要：Two piano-stool type mono-iron complexes featuring Cp*(N) (Cp*(N) = eta(5)-C5Me4(CF2)(2)NMe2) ligand were synthesized by one-electron oxidation of the corresponding dimer precursors. Furthermore, carbonyl ligand was smoothly replaced by MeCN molecule under illumination. Interestingly, the protonation of the amino group in the side chain led to dissociation of the nitrogen atom from the iron center. Reversibly, deprotonation by a weak base recovered the coordination capacity of the nitrogen atom. These results exhibit the function of the nitrogen atom in the second coordination sphere of some metalloenzymes as a potential proton relay site. (C) 2017 Elsevier B.V. All rights reserved.