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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
扫描关注
Synthesis of 6-(arylthio)phenanthridines by cyclization reaction of 2-isocyanobiphenyls with thiols
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论文类型：期刊论文
发表时间：2016-01-01
发表刊物：ARKIVOC
收录刊物：SCIE
页面范围：110-124
ISSN号：1551-7004
关键字：Phenanthridines; thiols; isocyanides; cyclization; radical reactions
摘要：An efficient method for the synthesis of 6-(arylthio)phenanthridines by tert-butyl peroxybenzoate (TBPB)-promoted cyclization reaction of 2-isocyanobiphenyls with thiols is developed. A radical pathway is proposed and evidenced for the reaction mechanism. It tolerates a wide range of substrates and represents a practical approach to 6-arylthiophenanthridines.