曲景平

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:日本东京大学

学位:博士

所在单位:化工学院

电子邮箱:qujp@dlut.edu.cn

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Asymmetric tandem Michael addition/oxidation of pyrazolones with p-benzoquinone catalyzed by cinchona alkaloids

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论文类型:期刊论文

发表时间:2015-12-15

发表刊物:TETRAHEDRON-ASYMMETRY

收录刊物:SCIE、Scopus

卷号:26

期号:23

页面范围:1382-1387

ISSN号:0957-4166

摘要:By employing a natural cinchona alkaloid as a catalyst, the enantioselective tandem Michael addition/oxidation of 4-substituted pyrazol-5-ones with p-benzoquinones was realized. The reaction afforded a wide range of 4,4-disubstituted pyrazol-5-ones with moderate to good yields (up to 72%) and moderate to good enantioselectivities (up to 99%). (C) 2015 Elsevier Ltd. All rights reserved.