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论文类型：期刊论文

发表时间：2010-04-14

发表刊物：TETRAHEDRON LETTERS

收录刊物：SCIE、Scopus

卷号：51

期号：15

页面范围：1982-1984

ISSN号：0040-4039

关键字：Allylic alcohol; Allylation; Cubane-type sulfido cluster; Boric acid

摘要：A highly efficient and regioselective allylation reaction of amines with allylic alcohols under mild conditions catalyzed by the cubane-type sulfido cluster [(Cp*Mo)(3)S4Pd(dba)][PF6] with H3BO3 as an additive has been developed. A variety of amines and allylic alcohols are investigated, and in the case of allylic alcohols bearing substituents at either alpha- or gamma-position only linear allylic amination products are obtained. (C) 2010 Elsevier Ltd. All rights reserved.