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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
扫描关注
Highly Efficient and Regioselective Allylation with Allylic Alcohols Catalyzed by [Mo3S4Pd(eta(3)-allyl)] Clusters
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论文类型：期刊论文
发表时间：2010-06-18
发表刊物：ORGANIC LETTERS
收录刊物：SCIE、PubMed、Scopus
卷号：12
期号：12
页面范围：2726-2729
ISSN号：1523-7060
摘要：A highly efficient and regioselective allylation reaction of amines and active methylene compounds directly using allylic alcohols under mild conditions catalyzed by the novel cubane-type sulfido [(Cp*Mo)(3)(mu(3)center dot S)(4)Pd(eta(3)-allyl)][PF6](2) clusters has been developed. A variety of allylic alcohols and nucleophiles including amines and active methylene compounds are investigated, and in the case of allylic alcohols bearing substituents at either the alpha- or gamma-position only linear products are obtained.