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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
Heterometallic cubane-type clusters [M ' Mo3S4] (M ' = Au, Ag and Cu): synthesis, structures and electrochemical properties
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论文类型：期刊论文
发表时间：2010-06-28
发表刊物：DALTON TRANSACTIONS
收录刊物：SCIE、EI、PubMed
卷号：39
期号：24
页面范围：5658-5663
ISSN号：1477-9226
摘要：The heterometallic cubane-type clusters [(Cp* Mo)(3)(mu(3)-S)(4)Au(PR3)][PF6][X] (Cp* = eta(5)-Me-C5(5); 2a: R = Ph, X = BF4; 2b: R = Cy, X = PF6; 2c: R = 'Bu, X = PF6), [(Cp*Mo)(3)(mu(3)-S)(4)Ag(PPh3)][PF6][OTf] (3, OTf = OSO2CF3) and [(Cp* Mo)(3)(mu(3)-S)(4)CuI][PF6] (4) have been prepared by the reaction of [(Cp*Mo)(3)(mu(2)-S)(3)(mu(3)-S)][PF6] (1) with complexes [(R3P) Au][X], [(Ph3P) Ag][OTf] and CuI, respectively. These clusters have been spectroscopically and crystallographically characterized. In addition, the electrochemical properties of clusters 2a, 2b, 2c and 4 are also discussed.