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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
Synthesis and reactions of novel triply thiolate-bridged diiron complexes [Cp*Fe(mu(2)-SR)(3)FeCp*] (Cp* = eta(5)-C5Me5; R = Et, Ph)
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论文类型：期刊论文
发表时间：2008-02-25
发表刊物：ORGANOMETALLICS
收录刊物：EI、SCIE
卷号：27
期号：4
页面范围：666-671
ISSN号：0276-7333
摘要：The novel thiolate-bridged diiron complexes [Cp*Fe(mu(2)-SR)(3)FeCp*] (1, R = Et; 2, R = Ph) have been obtained by the reaction of [Cp*FeCl](2) with LiSEt or LiSPh in THF. Treatment of 1 with CO or (CNBu)-Bu-t in THF gives complex [Cp*FeSEt(mu(2)-SEt)(2)FeCp*CO] (3) or [Cp*FeSEt(mu(2)-SEt)(2)FeCp*(CNBu)-Bu-t] (4), while reaction of 1 with (CNBu)-Bu-t in CH2Cl2 results in the formation of complex [Cl2Fe(mu(2)-SEt)(2)FeCp*(CNBu)-Bu-t] (5). These five complexes have been spectroscopically and crystallographically characterized. In addition, the formation of 5 indicates that this class of clusters might serve as carbon-halogen bond activation reagents (catalysts), and carbon-halogen bond cleavage reaction of 4 is also described.