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Palladium-catalyzed regioselective allylation of five-membered heteroarenes with allyltributylstannane

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2015-03-04

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、PubMed、SCIE

Volume: 51

Issue: 18

Page Number: 3842-3845

ISSN: 1359-7345

Abstract: Palladium-catalyzed allylation reactions of 2-(chloromethyl)thiophenes, 2-(chloromethyl) furans, and N-protected 2-(chloromethyl)-1H-pyrroles with allyltributylstannane were described in this study. This type of allylation reaction regioselectively occurred on the heteroarene rings to produce allylated dearomatization products or allylated heteroarenes with satisfactory yields.

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