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NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-01-01

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、SCIE

Volume: 50

Issue: 99

Page Number: 15730-15732

ISSN: 1359-7345

Abstract: We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regio-selectivity in terms of cosolvents and nucleophiles.

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