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NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

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Indexed by:期刊论文

Date of Publication:2014-01-01

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、Scopus

Volume:50

Issue:99

Page Number:15730-15732

ISSN No.:1359-7345

Abstract:We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regio-selectivity in terms of cosolvents and nucleophiles.

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