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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
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Palladium-Catalyzed Direct 1,4-Addition of Heteroarenes to alpha,beta-Unsaturated Ketones via C-H Activation
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论文类型：期刊论文
发表时间：2012-07-01
发表刊物：SYNLETT
收录刊物：SCIE、Scopus
卷号：23
期号：11
页面范围：1605-1608
ISSN号：0936-5214
关键字：palladium catalyst; direct conjugate addition; heteroarene; unsaturated ketone; C-H activation
摘要：Palladium-catalyzed direct conjugate additions of heteroarenes to alpha,beta-unsaturated ketones via C-H activation are described. The reactions of heteroarenes with alpha,beta-unsaturated ketones proceeded smoothly in the presence of PdCl2 as a catalyst under mild conditions to give the corresponding Michael adducts in moderate to excellent yields.