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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
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Palladium-catalyzed bisfunctionalization of active alkenes by beta-acetonitrile-alpha-allyl addition: application to the synthesis of unsymmetric 1,4-di(organo)fullerene derivatives
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论文类型：期刊论文
发表时间：2012-03-07
发表刊物：TETRAHEDRON LETTERS
收录刊物：SCIE、Scopus
卷号：53
期号：10
页面范围：1210-1213
ISSN号：0040-4039
关键字：beta-Acetonitrile-alpha-allyl addition; Bisfunctionalization of active alkenes; All-carbon quarternary center; Unsymmetric 1,4-disubstituted C-60
摘要：A new, efficient palladium-catalyzed bisfunctionalization of ethylidene malononitriles by addition of acetonitrile and allyl groups is developed for the construction of all-carbon quarternary and tertiary centers simultaneously. This methodology is successfully applied to the synthesis of unsymmetric 1,4-disubstituted C-60. (C) 2011 Elsevier Ltd. All rights reserved.