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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
Highly Efficient Cu(OAc)2-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes Leading to Single-Bonded [60]Fullerene Dimers
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论文类型：期刊论文
发表时间：2012-01-16
发表刊物：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物：SCIE、EI、Scopus
卷号：51
期号：3
页面范围：802-806
ISSN号：1433-7851
关键字：copper; dimerization; fullerenes; homogeneous catalysis; radical reactions
摘要：Dimers are a girl's best friend: The title reaction allows the formation of single-bonded fullerene dimers with extremely high chemical yield and high compatibility with various functional groups, which are highly soluble in organic solvents. The use of Cu(OAc)2 catalyst with dimethylformamide or acetonitrile as additives under air is the critical factor in achieving the highly efficient catalytic dimerization. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.