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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
Nanoporous Copper Metal Catalyst in Click Chemistry: Nanoporosity-Dependent Activity without Supports and Bases
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论文类型：期刊论文
发表时间：2011-12-01
发表刊物：ADVANCED SYNTHESIS & CATALYSIS
收录刊物：Scopus、SCIE
卷号：353
期号：17
页面范围：3095-3100
ISSN号：1615-4150
关键字：click reaction; heterogeneous catalysis; high reusability; nanoporous copper catalyst; tunable nanoporosity
摘要：Nanoporous copper (CuNPore) catalysts with tunable nanoporosity were fabricated from Cu30Mn70 alloy by controlling the de-alloying temperature under free corrosion conditions. The tunable nanoporosity of CuNPore led to a significant enhancement of catalytic activity in click chemistry without using any supports and bases. Characterization of CuNPore surface, high reusability, leaching experiment, and formation of nanostructured copper acetylide revealed that the click reaction occurred at the catalyst surface.
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