包明
个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:日本东北大学
学位:博士
所在单位:化工学院盘锦分院
办公地点:精细化工国家重点实验室E504
电子邮箱:mingbao@dlut.edu.cn
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Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via eta(3)-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization
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论文类型:期刊论文
发表时间:2011-10-07
发表刊物:ORGANIC LETTERS
收录刊物:PubMed、Scopus、SCIE
卷号:13
期号:19
页面范围:5402-5405
ISSN号:1523-7060
摘要:Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or pare-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via eta(3)-benzylpalladium Intermediates.