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教授

博士生导师

硕士生导师

性别:男

毕业院校:日本东北大学

学位:博士

所在单位:化工学院盘锦分院

办公地点:精细化工国家重点实验室E504

电子邮箱:mingbao@dlut.edu.cn

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New Application of N-Halosuccinimide/PPh3 for the Halogenation of Propargyl Alcohols to Haloallenes

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论文类型:期刊论文

发表时间:2009-01-01

发表刊物:SYNTHETIC COMMUNICATIONS

收录刊物:SCIE

卷号:39

期号:21

页面范围:3940-3949

ISSN号:0039-7911

关键字:Haloallene; N-halosuccinimide; preparation; propargyl alcohol; triphenylphisphine

摘要:An efficient and convenient new method has been developed for the preparation of haloallenes from propargyl alcohols by a reagent combination of N-halosuccinimide and triphenylphosphine. Chloroallenes 2 and bromoallenes 3 were obtained exclusively in moderate to good yields with regioselectivity.