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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
X-ray structure of trans-chloro(1-naphthyl) bis(triphenylphosphine)nickel(II) and its application for catalytic dehalogenation of aryl chlorides
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论文类型：期刊论文
发表时间：2009-01-01
发表刊物：JOURNAL OF COORDINATION CHEMISTRY
收录刊物：SCIE、Scopus
卷号：62
期号：17
页面范围：2824-2831
ISSN号：0095-8972
关键字：X-ray structure; Nickel complex; Dehalogenation; Aryl chlorides
摘要：X-ray structure of trans-chloro(1-naphthyl)bis(triphenylphosphine)nickel(II) (4) was determined. The complex crystallizes in the triclinic system, space group P 1 with a = 12.0623(3), b = 13.8844(4), c = 14.5261(4) angstrom, = 104.787(2), = 104.861(2), = 107.602(2)degrees, and Z = 2. Dehalogenation of aryl chlorides was successfully performed in isopropyl alcohol (IPA) by using 4 as a precatalyst in the absence of reducing agent. The dehalogenation proceeded smoothly at ambient temperature to provide desired arenes in almost quantitative yields.