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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
扫描关注
Carbocycle synthesis through facile and efficient palladium-catalyzed allylative de-aromatization of naphthalene and phenanthrene allyl chlorides
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论文类型：期刊论文
发表时间：2008-07-01
发表刊物：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物：SCIE、EI、PubMed
卷号：47
期号：23
页面范围：4366-4369
ISSN号：1433-7851
关键字：de-aromatization; naphthalenes; palladium; phenanthrenes; synthetic methods
摘要：(Chemical Equation Presented) Ring of truth: The palladium-catalyzed reaction of allyltributylstannane with naphthalene or phenanthrene derivatives bearing an allyl chloride group proceeds smoothly to provide de-aromatized products with unique structures (see scheme). These products are very stable and can be used as intermediates to give fused-ring systems. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.