NAME

冯秀娟

Paper Publications

Highly chemoselective reduction of imines using a AuNPore/PhMe2SiH/water system and its application to reductive amination
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  • Indexed by:

    Journal Papers

  • First Author:

    Takale, Balaram S.

  • Correspondence Author:

    Bao, M (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China.

  • Co-author:

    Tao, Shanmou,Yu, Xiaoqiang,Feng, Xiujuan,Jin, Tienan,Bao, Ming,Yamamoto, Yoshinori

  • Date of Publication:

    2015-09-30

  • Journal:

    TETRAHEDRON

  • Included Journals:

    SCIE、Scopus

  • Document Type:

    J

  • Volume:

    71

  • Issue:

    39,SI

  • Page Number:

    7154-7158

  • ISSN No.:

    0040-4020

  • Key Words:

    Amine; Imine; Heterogeneous catalysis; Nanoporous gold; Reductive amination

  • Abstract:

    An unusually strong affinity of unsupported nanoporous gold (AuNPore) towards aldimines and ketimines has been demonstrated. By using PhMe2SiH and water as a hydrogen source and AuNPore as a catalyst, ketimines and aldimines can be reduced to the corresponding amines in high chemical yields under mild conditions. This system was also applied to the reductive amination of aldehydes and ketones. (C) 2014 Elsevier Ltd. All rights reserved.

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