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论文类型：期刊论文

发表时间：2011-06-01

发表刊物：4th International Workshop on Organic Photoswitchable Multifunctional Molecules and Materials

收录刊物：SCIE、EI、CPCI-S

卷号：89

期号：3,SI

页面范围：330-335

ISSN号：0143-7208

关键字：Fluorescence; Dye; Two-photon absorption action cross section; Molecular switch; Bovine serum albumin; Stainer

摘要：Two novel quadrapolar stilbene fluorescent dyes with CN groups (DCNs) are reported. Photophysical properties such as fluorescence, intermolecular charge transfer, two-photon absorption action cross section (delta Phi) and fluorescence-response to bovine serum albumin (BSA) are investigated and discussed. The fluorescence emission is red-shifted and quenched with the increase in polarity of solvents. In aqueous buffer (pH 7.0), compound 1b has a large blue shift (74 nm) and 37-fold fluorescence enhancement when interacts with BSA. The response is noticeable by naked eyes. Cations, anions and DNA have no such responses. It is resulted from the change of environmental polarity from aqueous solution to hydrophobic cage in protein, and sequentially, the change in the effect of excited intermolecular charge transfer. (C) 2010 Elsevier Ltd. All rights reserved.