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论文类型：期刊论文

发表时间：2009-04-01

发表刊物：DYES AND PIGMENTS

收录刊物：SCIE、EI

卷号：81

期号：1

页面范围：58-62

ISSN号：0143-7208

关键字：BODIPY; Fluorescent dyes; PET; pH; Probe; Spectroscopic properties

摘要：Two novel fluorescent pH probes based on 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene dyes were configured as a "fluorophore-spacer-receptor" system. Their absorption and fluorescence properties were investigated in various solvents; in aqueous solution, based on their photo-induced electron transfer, the probes exhibited 3-fold (pH 8.70-4.93) and 14-fold (pH 9.02-3.29) fluorescence enhancement upon increase in the acidity of the solution, respectively. The probes can be used as fluorescent pH probes which are excitable with visible light; the pK(a) values of the probes were determined from the fluorescence changes. (C) 2008 Elsevier Ltd. All rights reserved.