|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
办公地点：大连市凌工路2号大连理工大学西部校区化工实验楼A301，邮编：116024
电子邮箱：liyang@dlut.edu.cn
论文成果
当前位置: 大连理工大学李杨... >> 科学研究 >> 论文成果Scandium-catalyzed synthesis of Si-H-containing syndiotactic polystyrene and its functionalized polymer carrying pendant perylene bisimide units
点击次数：
论文类型：期刊论文
发表时间：2016-03-15
发表刊物：JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
收录刊物：SCIE、EI、Scopus
卷号：54
期号：6
页面范围：735-739
ISSN号：0887-624X
关键字：functionalized; perylene bisimide; polystyrene; syndiotactic; synthesis
摘要：Si-H-containing syndiotactic polystyrene is synthesized by the direct polymerization of 4-vinyiphenyldimethylsilanol in the presence of a half-sandwich scandium catalyst system [(C5Me4SiMe3)Sc(CH2C6H4NMe2-o)2]/[Ph3C][B(C6F5)4]. By the one-step efficient hydrosilylation reaction, the perylene bisimide units are quantitatively linked to the Si-H-containing syndiotactic polystyrene backbone. The perylene bisimide units functionalized syndiotactic polystyrene exhibits liquid crystallinity, fluorescence, and electron transporting properties. ? 2015 Wiley Periodicals, Inc.