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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
办公地点：大连市凌工路2号大连理工大学西部校区化工实验楼A301，邮编：116024
电子邮箱：liyang@dlut.edu.cn
论文成果
当前位置: 大连理工大学李杨... >> 科学研究 >> 论文成果Cyclocopolymerization of 1,6-Heptadiene with Styrene Catalyzed by a Half-Sandwich Scandium Dialkyl Complex Bearing a Phosphine Oxide Side Arm
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论文类型：期刊论文
发表时间：2014-06-01
发表刊物：JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
收录刊物：SCIE、EI、Scopus
卷号：52
期号：11
页面范围：1509-1513
ISSN号：0887-624X
关键字：1; 6-heptadiene; copolymerization; cyclopolymerization; scandium; polystyrene
摘要：By use of a half-sandwich scandium dialkyl complex bearing cyclopentadienyl ligand with a phosphine oxide side arm [(C5Me4SiMe 2CH2P(O)Ph2)Sc(CH2SiMe 3)2] in the presence of [Ph3C][B(C 6F5)4], the cyclocopolymerization of 1,6-heptadiene with styrene has been achieved for the first time to afford a new family of cyclopolyolefins containing a six-membered ring (methylene-1,3- cyclohexane), a five-membered ring (ethylene-1,2-cyclopentane), and styrene-styrene units. Copyright © 2014 Wiley Periodicals, Inc.
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