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论文类型：期刊论文

发表时间：2013-01-01

发表刊物：JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY

收录刊物：SCIE、EI、Scopus

卷号：50

期号：3

页面范围：297-301

ISSN号：1060-1325

关键字：Chemical modification; epoxidized polybutadiene; hydroxylation; dihydric

摘要：A method is described for the preparation of functional polybutadiene (PB) with hydroxyl groups along the polymer chain. This material can be used directly or as the starting substrate for further polymerization in both academic and industrial processes. We have developed a convenient method to obtain a polymer with a narrow molecular weight distribution and with a known content of hydroxyl groups along the backbone. By controlling the hydroxylation reaction conditions, the appropriate molar ratios of THF, water and acid with the epoxide are 30, 15 and 1.5, respectively. By minimizing the crosslinking reaction, the desired PB was prepared and subsequently characterized.