Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2013-05-14

Journal: DALTON TRANSACTIONS

Included Journals: Scopus、EI、SCIE、PubMed

Volume: 42

Issue: 18

Page Number: 6478-6488

ISSN: 1477-9226

Abstract: Naphthalenediimide (NDI) was connected to the ligand of a cyclometalated Ir(III) complex (Ir-1) via a CuC triple bond to enhance the absorption in the visible region and to access long-lived triplet excited states. Ir(ppy) 2(bpy)[ PF6] (Ir-2, ppy = 2-phenylpyridine and bpy = 2,2'-bipyridine) was used as a model complex. The photophysical properties of the complexes were studied with steady state and timeresolved spectroscopy. Ir-1 shows strong absorption in the visible region (e = 11 000 M-1 cm(-1) at 542 nm) and in comparison Ir-2 shows typically weak absorption in the visible region (e < 3000 M-1 cm(-1) above 400 nm). Room temperature near IR emission at 732 nm (FP = 0.1%) was observed for Ir-1, which is attributed to the NDI localized emissive triplet excited state, by transient absorption spectra and DFT calculations on the spin density surface. The lifetime of the NDI-localized triplet excited state is up to 130.0 mu s, which is rarely reported for Ir(III) complexes. In comparison, Ir-2 shows phosphorescence at 578 nm and the triplet state lifetime is a typical value of 0.3 mu s. The complexes were used as triplet photosensitizers for triplet-triplet annihilation (TTA) upconversion and an upconversion quantum yield of 6.7% was observed with Ir-1. No upconversion was observed with Ir-2 as the triplet photosensitizer at the same experimental conditions.