Hits:
Indexed by:期刊论文
Date of Publication:2012-02-07
Journal:RSC ADVANCES
Included Journals:Scopus、SCIE、EI
Volume:2
Issue:3
Page Number:1061-1067
ISSN No.:2046-2069
Abstract:Difluoroboron (BF2) bound phenylacetylide was attached to the Pt(II) center of (NN)-N-boolean AND Pt(II) bisacetylide complex (Pt-1). Enhanced absorption in the visible region (epsilon = 1.37 x 10(4) M-1 cm(-1) at 434 nm) and emissive (IL)-I-3 excited state (tau = 0.92 mu s, Phi = 3.3%) were observed for Pt-1, compared to the model complex dbbpy Pt(II) bisphenylacetylide (Pt-2, tau = 0.90 ms, Phi = 40.0%. dbbpy = 4,4'-di-tertbutyl- 2,2'-bipyridine). Pt-1 was used as the triplet sensitizer for triplet-triplet annihilation (TTA) based upconversion and an upconversion quantum yield (Phi(UC)) of 8.9% was observed with 9,10-diphenylanthracence (DPA) as the triplet acceptor. In comparison, no upconversion was observed for the model complex Pt-2.
Pre One:Fluorescent coumarin derivatives with large stokes shift, dual emission and solid state luminescent properties: An experimental and theoretical study
Next One:Long-Lived Room-Temperature Near-IR Phosphorescence of BODIPY in a Visible-Light-Harvesting N C N PtII-Acetylide Complex with a Directly Metalated BODIPY Chromophore
