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Ruthenium(II) Polyimine-Coumarin Dyad with Non-emissive (IL)-I-3 Excited State as Sensitizer for Triplet-Triplet Annihilation Based Upconversion

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Indexed by:期刊论文

Date of Publication:2011-08-29

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:PubMed、Scopus、SCIE、EI

Volume:50

Issue:36

Page Number:8283-8286

ISSN No.:1433-7851

Key Words:coumarin; electronic structure; photochemistry; ruthenium; upconversion

Abstract:Light out of darkness? Most sensitizers for triplet-triplet annihilation (TTA) upconversion are strongly phosphorescent. A new RuII-coumarin dyad, on the other hand, has a non-emissive 3IL excited state (φP=0.2%) but shows a good upconversion quantum yield (φUC=2.7%, see picture, TTET=triplet-triplet energy transfer). © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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