个人信息Personal Information
副教授
硕士生导师
性别:女
毕业院校:Regensburg大学
学位:博士
所在单位:化学学院
学科:分析化学
电子邮箱:guohm@dlut.edu.cn
Room-Temperature Long-Lived Triplet Excited States of Naphthalenediimides and Their Applications as Organic Triplet Photosensitizers for Photooxidation and Triplet-Triplet Annihilation Upconversions
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论文类型:期刊论文
发表时间:2012-04-20
发表刊物:JOURNAL OF ORGANIC CHEMISTRY
收录刊物:SCIE、EI、PubMed、Scopus
卷号:77
期号:8
页面范围:3933-3943
ISSN号:0022-3263
摘要:Naphthalenediimide (NDI) derivatives with 2,6- or 2,3,6,7-tetrabromo or amino substituents were prepared. N,N'-dialkyl-2,6-dibromo NDI (compound 2) and N,N'-dialkyl-2,3,6,7-tetrabromo NDI (compound 4) show phosphorescence emission at 610 or 667 nm, respectively. Phosphorescence was never observed for NDI derivatives. Conversely, N,N'-dialkyl-2,6-dibromo-3,7-diamino NDI (compound 5) shows strong absorption at 526 nm and fluorescence at 551 nm, and no phosphorescence was observed. However, nanosecond time-resolved transient difference absorption spectroscopy confirmed that the triplet excited state of 5 was populated upon photoexcitation. 2,3,6,7-Tetraamino NDI (6) shows fluorescence, and no triplet excited state was populated upon excitation. The compounds were used as singlet oxygen (O-1(2)) photosensitizers for the photooxidation of 1,5-dihydroxylnaphthalene (DHN). We found that 5 is more efficient than the conventional photosensitizer, such as Ir(ppy)(2)(bpy)[PF6]. The compounds were also used as organic triplet photosensitizers for triplet triplet annihilation based upconversions. An upconversion quantum yield up to 18.5% was observed.
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