郭慧敏

个人信息Personal Information

副教授

硕士生导师

性别:女

毕业院校:Regensburg大学

学位:博士

所在单位:化学学院

学科:分析化学

电子邮箱:guohm@dlut.edu.cn

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Ruthenium(II) Polyimine-Coumarin Dyad with Non-emissive (IL)-I-3 Excited State as Sensitizer for Triplet-Triplet Annihilation Based Upconversion

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论文类型:期刊论文

发表时间:2011-08-29

发表刊物:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

收录刊物:PubMed、Scopus、SCIE、EI

卷号:50

期号:36

页面范围:8283-8286

ISSN号:1433-7851

关键字:coumarin; electronic structure; photochemistry; ruthenium; upconversion

摘要:Light out of darkness? Most sensitizers for triplet-triplet annihilation (TTA) upconversion are strongly phosphorescent. A new RuII-coumarin dyad, on the other hand, has a non-emissive 3IL excited state (φP=0.2%) but shows a good upconversion quantum yield (φUC=2.7%, see picture, TTET=triplet-triplet energy transfer). © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.