梁长海

个人信息Personal Information

教授

博士生导师

硕士生导师

任职 : 大连理工大学成都研究院院长

性别:男

毕业院校:中科院大连化学物理研究所

学位:博士

所在单位:化工学院

学科:化学工艺. 物理化学. 功能材料化学与化工

办公地点:大连理工大学西部校区化工综合楼A401室

联系方式:辽宁省大连市高新区凌工路2号,邮编116024

电子邮箱:changhai@dlut.edu.cn

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论文成果

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In situ synthesis of Au-Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene

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论文类型:期刊论文

发表时间:2014-01-01

发表刊物:RSC ADVANCES

收录刊物:EI、SCIE、Scopus

卷号:4

期号:89

页面范围:48254-48259

ISSN号:2046-2069

摘要:Highly dispersed Au-Pd nanoparticles (NPs) with an average size of similar to 3.0 nm were synthesized by in situ reduction of HAuCl4 and PdCl2 on an amine-functionalized SiO2 support. The structural and electronic properties of the Au-Pd NPs were investigated systematically using STEM-EDX, XRD, UV-vis and XPS spectroscopy. It is demonstrated that the composition of the Au-Pd NPs can be tuned by varying the ratio of Au- to Pd-containing salt in solution. In the aqueous-phase hydrodechlorination of chlorobenzene, the Au-Pd NPs showed a much higher activity and chlorine resistance than the monometallic Au and Pd counterparts. The effects of base and solvent on the activity over the supported Au-Pd NPs were also investigated.