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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 大连理工大学成都研究院院长
性别:男
毕业院校:中科院大连化学物理研究所
学位:博士
所在单位:化工学院
学科:化学工艺. 物理化学. 功能材料化学与化工
办公地点:大连理工大学西部校区化工综合楼A401室
联系方式:辽宁省大连市高新区凌工路2号,邮编116024
电子邮箱:changhai@dlut.edu.cn
In situ synthesis of Au-Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene
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论文类型:期刊论文
发表时间:2014-01-01
发表刊物:RSC ADVANCES
收录刊物:EI、SCIE、Scopus
卷号:4
期号:89
页面范围:48254-48259
ISSN号:2046-2069
摘要:Highly dispersed Au-Pd nanoparticles (NPs) with an average size of similar to 3.0 nm were synthesized by in situ reduction of HAuCl4 and PdCl2 on an amine-functionalized SiO2 support. The structural and electronic properties of the Au-Pd NPs were investigated systematically using STEM-EDX, XRD, UV-vis and XPS spectroscopy. It is demonstrated that the composition of the Au-Pd NPs can be tuned by varying the ratio of Au- to Pd-containing salt in solution. In the aqueous-phase hydrodechlorination of chlorobenzene, the Au-Pd NPs showed a much higher activity and chlorine resistance than the monometallic Au and Pd counterparts. The effects of base and solvent on the activity over the supported Au-Pd NPs were also investigated.