location： Current position: Home >> Scientific Research >> Paper Publications

M4L4 cerium cages assembled from ligands with lower symmetry as a molecular flask

Hits:

Indexed by:期刊论文

Date of Publication:2014-01-01

Journal:INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals:SCIE

Volume:39

Page Number:147-150

ISSN No.:1387-7003

Key Words:Cages; Molecular flask; Cyanosilylation

Abstract:Cerium-based tetranuclear polyhedra Ce-YB1 and Ce-YB2 assembled from lower symmetrical ligands without three fold axle, can work as molecular flasks to catalyze cyanosilylation reactions of aldehyde molecules with suitable sizes. The size-selectively catalytic behavior of the cages was investigated by using large aldehydes as the substrate, based on which the corresponding cyanosilylation reactions could not be carried out on the same condition. (C) 2013 Published by Elsevier B.V.

Pre One:Cerium-based M4L4 tetrahedrons containing hydrogen bond groups as functional molecular flasks for selective reaction prompting

Next One:Proline adducts of metallo-organic, sextuply-stranded lanterns as homogeneous catalysts for asymmetric catalysis
Institutional Repository Personal Page

Address: No.2 Linggong Road, Ganjingzi District, Dalian City, Liaoning Province, P.R.C., 116024

Click : times
  • MOBILE Version
    •
    Open time:..
    The Last Update Time:..

    Mobile phone sweep