Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2013-12-02

Journal: TETRAHEDRON

Included Journals: Scopus、SCIE

Volume: 69

Issue: 48

Page Number: 10477-10481

ISSN: 0040-4020

Key Words: Metallo-organic polyhedron; Chirality; Proline; Asymmetric catalysis; Cyanosilylation

Abstract: Two homochiral metal-organic, sextuply-stranded, lantern-like complexes, Ce-L-Pro1 and Ce-D-Pro1, were synthesized via self-assembly by incorporating a L or D-pyrrolidine moiety within the respective ligands. The Ce-Pro1 complexes are comprised of chiral pyrrolidine-containing ligands and have lantern-like cavities. They function as asymmetric catalysts that promote cyanosilylation reactions with good conversions and enantioselectivity. (C) 2013 Published by Elsevier Ltd.