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Indexed by:期刊论文

Date of Publication:2013-12-02

Journal:TETRAHEDRON

Included Journals:SCIE、Scopus

Volume:69

Issue:48

Page Number:10477-10481

ISSN No.:0040-4020

Key Words:Metallo-organic polyhedron; Chirality; Proline; Asymmetric catalysis; Cyanosilylation

Abstract:Two homochiral metal-organic, sextuply-stranded, lantern-like complexes, Ce-L-Pro1 and Ce-D-Pro1, were synthesized via self-assembly by incorporating a L or D-pyrrolidine moiety within the respective ligands. The Ce-Pro1 complexes are comprised of chiral pyrrolidine-containing ligands and have lantern-like cavities. They function as asymmetric catalysts that promote cyanosilylation reactions with good conversions and enantioselectivity. (C) 2013 Published by Elsevier Ltd.