NAME

何成

Paper Publications

Synthesis, structure, and magnetic properties of a cyanidebridged Fe(III)-Cu(II) bimetallic double-zigzag chain with slow relaxation of the magnetization
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  • Indexed by:

    期刊论文

  • First Author:

    Dong DaPeng

  • Correspondence Author:

    Liu, T (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China.

  • Co-author:

    Zheng Hui,Zhao Liang,Zhuang PengFei,Liu Tao,He Cheng,Duan ChunYing

  • Date of Publication:

    2012-06-01

  • Journal:

    SCIENCE CHINA-CHEMISTRY

  • Included Journals:

    SCIE、EI

  • Document Type:

    J

  • Volume:

    55

  • Issue:

    6

  • Page Number:

    1018-1021

  • ISSN No.:

    1674-7291

  • Key Words:

    single chain magnet; double-zigzag chain; ferromagnetic coupling

  • Abstract:

    Using Bu4N[Fe(Tp*)(CN)(3)](-) (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) as the building block to react with Cu-II and N-methylimidazole, we obtained a one-dimensional (1D) heterobimetallic cyano-bridged chain, [Fe(Tp*)(CN)(3)](2)Cu(N-methylimidazole)(2)center dot 2H(2)O (1). The crystal structures and magnetic studies demonstrate that complex 1 exhibits slow relaxation of the magnetization due to strong intrachain ferromagnetic coupling and weak interchain interactions.

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