期刊论文
Dong, Da-Peng
Liu, T (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China.
Liu, Tao,Kanegawa, Shinji,Kang, Soonchul,Sato, Osamu,He, Cheng,Duan, Chun-Ying
2012-05-21
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
SCIE、EI、PubMed、Scopus
J
51
21
5119-5123
1433-7851
chain structures; charge transfer; cobalt; iron; magnetic properties
Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated FeIII2CoII chains of {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2} 2H 2O 2CH3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.