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Indexed by:期刊论文

Date of Publication:2012-05-21

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:SCIE、EI、PubMed、Scopus

Volume:51

Issue:21

Page Number:5119-5123

ISSN No.:1433-7851

Key Words:chain structures; charge transfer; cobalt; iron; magnetic properties

Abstract:Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated FeIII2CoII chains of {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2} 2H 2O 2CH3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.