Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-05-21

Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 51

Issue: 21

Page Number: 5119-5123

ISSN: 1433-7851

Key Words: chain structures; charge transfer; cobalt; iron; magnetic properties

Abstract: Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated FeIII2CoII chains of {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2} 2H 2O 2CH3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.