A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C-H alkylation of aliphatic nitriles
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论文类型：期刊论文
发表时间：2016-03-28
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：PubMed、SCIE
卷号：52
期号：25
页面范围：4714-4717
ISSN号：1359-7345
摘要：The efficient photosensitizing of decatungstate-based MOF with 1D channels was achieved via in situ synthesis under solvothermal conditions for light driven acceleration of beta- or gamma-site C-H alkylation of aliphatic nitriles. The high catalytic efficiency, excellent size selectivity, high stability and good recyclability of the photocatalyst offer an environmentally-friendly route for widening the scope of accessible nitriles in both laboratory and industry.