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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：南京大学
学位：博士
所在单位：化工学院
电子邮箱：hecheng@dlut.edu.cn
Two octacyanometallate based (WNiII)-Ni-V and (MoNiII)-Ni-V chains with dominant ferromagnetic interactions
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论文类型：期刊论文
发表时间：2015-07-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE
卷号：57
页面范围：29-32
ISSN号：1387-7003
关键字：Cyanide; Building block; Ferromagnetic; Octacyanometallate
摘要：The preparation, single-crystal X-ray crystallography and magnetic properties are reported for two single-zigzag chain complexes {[W(CN)(8)][Ni(imi)(4)]}center dot Bu4N center dot CH3OH center dot 2H(2)O (1) and {[Mo(CN)(8)][Ni(imi)(4)]}center dot Bu4N center dot 2H(2)O (2) (imi = imidazole, Bu = normal-butyl). The structure studies reveal that both complexes feature one-dimension anion chains linked by [W(CN)(8)](3-) units in 1 or [Mo(CN)(8)](3-) units in 2. Magnetic studies show that strong ferromagnetic exchange is operative within the W-V(mu-CN)Ni-II units for (1) and Mo-V(mu-CN)Ni-II units for (2). (C) 2015 Elsevier B.V. All rights reserved.