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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：南京大学
学位：博士
所在单位：化工学院
电子邮箱：hecheng@dlut.edu.cn
Two cyano-bridged {(Fe4M2II)-M-III}c (M = Fe-II, Co-II) hexanuclear complexes with dominant ferromagnetic interactions
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论文类型：期刊论文
发表时间：2015-07-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE、Scopus
卷号：57
页面范围：33-35
ISSN号：1387-7003
关键字：Self-assembly; Cyanide; Hexanuclear; Ferromagnetic
摘要：Two hexanuclear complexes of formula [Fe-III(Tp*)(CN)(3)](4)[Fe-II(tptz)](2) (1), [Fe-III(Tp*)(CN)(3)](4)[Co-II(tptz)](2) (2) [Tp* = hydridotris(3,5-dimethylpyrazolyl)borate, tptz = (2,4,6-tris-(2-pyridyl)1,3,5-triazine] have been synthesized via directional assembly of metallocyanate precursor and metal cationic ions. The magnetic properties characterization indicate that ferromagnetic interactions dominate in the two complexes, resulting in a spin ground state of S = 5 and S = 6, respectively. (C) 2015 Elsevier B.V. All rights reserved.