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论文类型：期刊论文

发表时间：2011-03-15

发表刊物：TALANTA

收录刊物：SCIE、EI、PubMed

卷号：84

期号：1

页面范围：53-59

ISSN号：0039-9140

关键字：Fluorescence dye; Hg2+; Silica material; Absorbent; Toxicide

摘要：A novel hybrid material (SBA-P1) is prepared through the functionalization of mesoporous silica (SBA-15) with a 1,8-naphthalimide-based dye by sol-gel reaction. The characterization results of elemental analysis (EA), X-ray powder diffractometer (XRD) and spectroscopic methods demonstrate the fluorescence dye P1 is successfully grafted onto the inner surface of SBA-15 and the organized structure is preserved. SBA-P1 can detect Hg2+ with high selectivity to Cu2+, Zn2+, Cd2+, Pb2+, Mn2+, Ni2+, Co2+, Ag+, Cr3+, and Mg2+, Ca2+, Li+, Na+, K+ in water and sensitivity to environmentally relevant mercury in complex natural samples. The quenching fluorescence detection is also reversible by treating with EDTA/base. Furthermore, its fluorescence intensity keeps stable in the physiologically relevant pH range. The extraction ability of SBA-P1 is also estimated by inductively coupled plasma source mass spectrometer (ICP), showing that approximately 90% of the Hg2+ ion is extracted. These results imply that the hybrid material has potential application for sensing and removing of Hg2+ ions in waste water and working as toxicide for acute mercury poisoning. (C) 2010 Elsevier B.V. All rights reserved.