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Ion-enrichment and ion-depletion of nanochannels based on electrochemical potential in a micro-nanofluidic chip

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Indexed by:期刊论文

Date of Publication:2014-01-01

Journal:MICROSYSTEM TECHNOLOGIES-MICRO-AND NANOSYSTEMS-INFORMATION STORAGE AND PROCESSING SYSTEMS

Included Journals:SCIE、EI、Scopus

Volume:20

Issue:1

Page Number:35-39

ISSN No.:0946-7076

Abstract:In this paper, we present a new approach for ion-enrichment and ion-depletion effect (IEID) in micro-nanofluidic chips without external power source. The method utilizes different reducibility of various electrodes in the weak oxidizing solution to generate the electrochemical potential and then induce IEID at a micro-nano junction. The results show that the average gray values of the micro-nano junction based on Al-Pt, Fe-Pt, and Cu-Pt electrodes increase from 14.7 to 40.2, 27.1, 15.0 after 20 s, and electric currents for Al-Pt, Fe-Pt, and Cu-Pt electrodes are 5.0, 2.9 and 0 nA respectively. Metal cations generating from oxidation-reduction reaction and electroosmotic convection flow are evaluated and their influences to IEID can be neglected in this case. The IEID method based on the electrochemical potential is power-free and weak flow convective that will be beneficial to the integrity of micro-nanofluidic chips and stability of IEID.

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