安海艳
Associate Professor Supervisor of Doctorate Candidates Supervisor of Master's Candidates
Gender:Female
Alma Mater:Northeast Normal University
Degree:Doctoral Degree
School/Department:College of Chemistry
Discipline:Inorganic Chemistry
Business Address:Chemical Complex Building C406
Contact Information:13664256422
E-Mail:anhy@dlut.edu.cn
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Indexed by:期刊论文
Date of Publication:2010-01-01
Journal:JOURNAL OF COORDINATION CHEMISTRY
Included Journals:SCIE、Scopus
Volume:63
Issue:17
Page Number:3028-3041
ISSN No.:0095-8972
Key Words:Dawson-type phosphomolybdate; Alkali-metal coordination complex; Lanthanide coordination complex; 1-D chain; Supramolecular channel
Abstract:In this study, a series of compounds based on Dawson-type phosphomolybdates, H3(C6NO2H6)2[K(H2O)3(C6NO2H5)3][P2Mo18O62] 5.5H2O (1), (C6NO2H6)6[Ln(H2O)7(C6NO2H5)2]2[P2Mo18O62]2 center dot 13.5H2O (Ln = Ce (2), La (3)) have been synthesized and characterized by elemental analysis, IR and UV-Vis spectroscopy methods, TG analysis, and single-crystal X-ray diffraction. Compound 1 consists of [P2Mo18O62]6- building units joined by potassium-pyridine-3-carboxylic acid complexes, resulting in a wavelike polyoxometalate (POM) chain, which further interacts with each other via intermolecular interactions to form a 3-D supramolecular channel framework containing guest water molecules. Compounds 2 and 3 possess a 3-D supramolecular framework with 1-D tunnel constructed from [P2Mo18O62]6- and mononuclear lanthanide coordination complex fragments. To the best of our knowledge, 1 not only represents the first example of 1-D hybrid assembly based on Dawson-type phosphomolybdate, but also the first hybrid compound constructed from Dawson-type POMs and alkali-metal coordination complex fragments.
In 2002, Prof. Haiyan An received the B.S. degree in chemistry Northeast Normal University, Changchun, China; the M.S. in 2004 and the Ph.D. degree in 2007 in Key Laboratory of Polyoxometalates (POMs) Science of Ministry of Education. There were 30 papers published in Angew. Chem. Int. Ed., Inorg. Chem., Cryst. Growth Des., etc. during the degree. In 2006, she was awarded the Excellent Doctoral Dissertations Fund of Northeast Normal University. In July 2007, Prof. An joined College of Chemistry, Dalian University of Technology in the field of POMs. Her research interests are mainly focuse on the design, synthesis and properties’research of POM-based functional complexes with catalytic and drug activity. She has Undertaked two National Natural Science Foundation of China, one Specialized Research Fund for the Doctoral Program of Higher Education, one Natural Science foundation of Liaoning Province and one Scientific Research Foundation for Doctor of Liaoning Province. There are more than 30 SCI papers have been officially published in foreign periodicals during the work period, more than 20 of which list her as the first author and corresponding author.
