Indexed by:期刊论文

Date of Publication:2012-01-01

Journal:MICROPOROUS AND MESOPOROUS MATERIALS

Included Journals:SCIE、EI

Volume:147

Issue:1

Page Number:295-301

ISSN No.:1387-1811

Key Words:Multifunctional microsphere; Pollutants sequential sorption; Magnetic removal

Abstract:A novel magnetic microsphere with thiol-functionalized mesoporous shell was fabricated by using a colloidal chemical method and cationic surfactants (CTAB) as structure-directing agents. As a high performance adsorbent, these microspheres were examined for environmental protection applications to adsorb and remove toxic phenolic compounds and heavy metal ions, sequentially, in aqueous solution. The prepared nanocomposite microspheres were mesoporous and magnetizable, with a diameter of 350-400 nm, a high surface area of 913.14 m(2)/g, a pore size of 2.48 nm, and a saturation magnetization of 33.9 emu/g. These multifunctional microspheres showed excellent adsorptive capability towards toxic phenolic compounds and heavy metal ions (Hg(2+), Pb(2+)). The cation micelle made of CTAB in the mesopores has great attractive power to phenolic compounds and the adsorption capacity was as high as 144.78 mg/g for 4-methyl-2,6-dinitrophenol. The thiol-functionalized magnetic mesoporous microsphere (TMMM) which had adsorbed phenolic compounds can further adsorb metal ions after removing (TAB. The adsorption capacity was 185.19 mg/g for Hg(2+) and 114.7 mg/g for Pb(2+). The TMMM can be easily removed from solution by an external magnetic field. These results suggest that this kind of nanocomposites is potentially useful materials for effectively adsorbing and removing different dangerous pollutants in aqueous solution. Crown Copyright (C) 2011 Published by Elsevier Inc. All rights reserved.