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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：化学学院副院长
其他任职：辽宁省教学名师，宝钢优秀教师特等奖提名奖，中国分析测试学会青年学术委员会委员
性别：女
毕业院校：南京大学
学位：博士
所在单位：化学学院
学科：分析化学. 生物化学与分子生物学
办公地点：化工综合楼C305
电子邮箱：wushuo@dlut.edu.cn
An electrochemically aminated glassy carbon electrode for simultaneous determination of hydroquinone and catechol
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论文类型：期刊论文
发表时间：2016-02-07
发表刊物：ANALYST
收录刊物：SCIE、PubMed
卷号：141
期号：3
页面范围：1077-1082
ISSN号：0003-2654
摘要：In this contribution, a very simple and reliable strategy based on the easy modification of a glassy carbon electrode (GCE) by pre-electrolyzing GCE in ammonium carbamate aqueous solution was employed for the simultaneous determination of hydroquinone (HQ) and catechol (CC). Compared with bare GCE, the incorporation of nitrogen into the GCE surface structure improved the electrocatalytic properties of GCE towards the electro-oxidation of HQ and CC. The nitrogen-introduced GCE (N-GCE) was evaluated for the simultaneous detection of HQ and CC and the linear ranges for HQ and CC were both from 5 to 260 mu M. Their detection limits were both evaluated to be 0.2 mu M (S/N = 3). The present method was applied for the determination of HQ and CC in real river water samples with recoveries of 95.0-102.1%. In addition, a possible detection mechanism of HQ and CC was discussed.